# Direct reduced iron

(Redirected from Sponge iron)

Direct reduced iron (DRI), also called sponge iron,[1] is produced from the direct reduction of iron ore (in the form of lumps, pellets, or fines) to iron by a reducing gas or elemental carbon produced from natural gas or coal. Many ores are suitable for direct reduction.

Reduced iron derives its name from the chemical change that iron ore undergoes when it is heated in a furnace at high temperatures in the presence of hydrocarbon-rich gases, carbon monoxide, or elemental carbon. Direct reduction refers to processes which reduce iron oxides to metallic iron at temperatures below the melting point of iron. The product of such solid state processes is called direct reduced iron.

The reducing gas is a mixture of gases, primarily hydrogen (H2) and carbon monoxide (CO). The process temperature is typically 800 to 1200 °C.[2]

## Process

Direct reduction processes can be divided roughly into two categories: gas-based, and coal-based. In both cases, the objective of the process is to drive off the oxygen contained in various forms of iron ore (sized ore, concentrates, pellets, mill scale, furnace dust, etc.), in order to convert the ore to metallic iron, without melting it (below 1200 °C).

The direct reduction process is comparatively energy efficient. Steel made using DRI requires significantly less fuel, in that a traditional blast furnace is not needed. DRI is most commonly made into steel using electric arc furnaces to take advantage of the heat produced by the DRI product.[3]

### Benefits

In modern times, direct reduction processes have been developed to specifically overcome the difficulties of conventional blast furnaces. DRI is successfully manufactured in various parts of the world. The initial investment and operating costs of direct reduction plants are low compared to integrated steel plants and are more suitable for developing countries where supplies of coking coal are limited.

Factors that help make DRI economical:

• Direct-reduced iron has about the same iron content as pig iron, typically 90–94% total iron (depending on the quality of the raw ore) so it is an excellent feedstock for the electric furnaces used by mini mills, allowing them to use lower grades of scrap for the rest of the charge or to produce higher grades of steel.
• Hot-briquetted iron (HBI) is a compacted form of DRI designed for ease of shipping, handling and storage.
• Hot direct reduced iron (HDRI) is iron not cooled before discharge from the reduction furnace, that is immediately transported to a waiting electric arc furnace and charged, thereby saving energy.
• The direct reduction process uses pelletized iron ore or natural "lump" ore. One exception is the fluidized bed process which requires sized iron ore particles.
• The direct reduction process can use natural gas contaminated with inert gases, avoiding the need to remove these gases for other use. However, any inert gas contamination of the reducing gas lowers the effect (quality) of that gas stream and the thermal efficiency of the process.
• Supplies of powdered ore and raw natural gas are both available in areas such as Northern Australia, avoiding transport costs for the gas. In most cases the DRI plant is located near natural gas source as it is more cost effective to ship the ore rather than the gas.
• This method produces 97% pure iron.

India is the world’s largest producer of direct-reduced iron, a vital constituent of the steel industry.[4] Many other countries use variants of the process, so providing iron for local engineering industries.

### Problems

Direct reduced iron is highly susceptible to oxidation and rusting if left unprotected, and is normally quickly processed further to steel.[citation needed] The bulk iron can also catch fire since it is pyrophoric.[5] Unlike blast furnace pig iron, which is almost pure metal, DRI contains some siliceous gangue, which needs to be removed in the steel-making process.

## History

Producing sponge iron and then working it was the earliest method used to obtain iron in the Middle East, Egypt, and Europe, where it remained in use until at least the 16th century. There is some evidence that the bloomery method was also used in China, but China had developed blast furnaces to obtain pig iron by 500 BCE.

The advantage of the bloomery technique is that iron can be obtained at a lower furnace temperature, only about 1,100 °C or so. The disadvantage, relative to a blast furnace, is that only small quantities can be made at a time.

## Chemistry

The following carbothermic reactions reduce iron ore to iron.[6]

hematite becomes magnetite by reduction with carbon monoxide and hydrogen

${\displaystyle {\ce {3 Fe2O3 + CO -> 2 Fe3O4 + CO2}}}$

${\displaystyle {\ce {3 Fe2O3 + H2O}}}$

magnetite becomes ferrous oxide by reduction with carbon monoxide and hydrogen

${\displaystyle {\ce {Fe3O4 + CO -> 3 FeO + CO2}}}$

${\displaystyle {\ce {Fe3O4 + H2 -> 3 FeO + H2O}}}$

ferrous oxide becomes sponge iron by reduction with carbon monoxide and hydrogen

${\displaystyle {\ce {FeO + CO -> Fe + CO_2}}}$

${\displaystyle {\ce {FeO + H2 -> Fe + H2O}}}$

carburizing produces cementite

${\displaystyle {\ce {3 Fe + CH4 -> Fe3C + 2H2}}}$

${\displaystyle {\ce {3 Fe + 2CO -> Fe3C + CO2}}}$

${\displaystyle {\ce {3 Fe + CO +H2 -> Fe3C + H2O}}}$

## Uses

Sponge iron is not useful by itself, but can be processed to create wrought iron. The sponge is removed from the furnace, called a bloomery, and repeatedly beaten with heavy hammers and folded over to remove the slag, oxidise any carbon or carbide and weld the iron together. This treatment usually creates wrought iron with about three percent slag and a fraction of a percent of other impurities. Further treatment may add controlled amounts of carbon, allowing various kinds of heat treatment (e.g. "steeling").

Today, sponge iron is created by reducing iron ore without melting it. This makes for an energy-efficient feedstock for specialty steel manufacturers which used to rely upon scrap metal.

## References

Notes
1. ^ "What is direct reduced iron (DRI)? definition and meaning". Businessdictionary.com. Retrieved 2011-07-11.
2. ^ "Direct reduced iron (DRI)". International Iron Metallics Association.
3. ^ R. J. Fruehan, et al. (2000). Theoretical Minimum Energies to Produce Steel (for Selected Conditions)
4. ^ "2017 World Direct Reduction Statistics" (PDF). Midrex Technologies. 2017. Retrieved May 31, 2018.
5. ^ Hattwig, Martin; Steen, Henrikus (2004), Handbook of explosion prevention and protection, Wiley-VCH, pp. 269–270, ISBN 978-3-527-30718-0.
6. ^ "MIDREX" (PDF).
Bibliography
• Valipour MS, and Saboohi, Y, "Numerical investigation of nonisothermal reduction of hematite using Syngas: the shaft scale study", Modelling Simul. Mater. Sci. Eng. 15(5), p. 487, 2007: http://iopscience.iop.org/0965-0393/15/5/008.
• Valipour, MS, "Mathematical Modeling of a Non-Catalytic Gas-Solid Reaction: Hematite Pellet Reduction with Syngas", Scientia Iranica, 16(2c), 108-124, 2009: http://sid.ir/en/VEWSSID/J_pdf/955200902C10.pdf.
• Grobler, F. and Minnitt, R.C.A "The increasing role of direct reduced iron in global steelmaking", The Australasian Institute of Mining and Metallurgy: http://www.hannansreward.com/reports/120964-990304-Increasing-iron-role.pdf