Sodium dithionite

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Sodium dithionite
Sodium dithionite
Sodium-dithionite-xtal-1992-3D-balls.png
Sample of sodium dithionite.jpg
Names
Other names
D-Ox
Hydrolin
Reductone
Sodium hydrosulfite
Sodium sulfoxylate
Sulfoxylate
Vatrolite
Virtex L
Identifiers
  • 7775-14-6 YesY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:66870 No
ChemSpider
  • 22897
ECHA InfoCard 100.028.991
EC Number 231-890-0
PubChem CID
  • 24489
RTECS number JP2100000
UN number 1384
Properties
Na2S2O4
Molar mass 174.107 g/mol (anhydrous)
210.146 g/mol (dihydrate)
Appearance white to grayish crystalline powder
light-lemon colored flakes
Odor faint sulfur odor
Density 2.38 g/cm3 (anhydrous)
1.58 g/cm3 (dihydrate)
Melting point 52 °C (126 °F; 325 K)
Boiling point Decomposes
18.2 g/100 mL (anhydrous, 20 °C)
21.9 g/100 mL (Dihydrate, 20 °C)
Solubility slightly soluble in alcohol
Hazards
Harmful (Xn)
R-phrases (outdated) R7, R22, R31
S-phrases (outdated) (S2), S7/8, S26, S28, S43
NFPA 704
Flammability code 3: Liquids and solids that can be ignited under almost all ambient temperature conditions. Flash point between 23 and 38 °C (73 and 100 °F). E.g., gasoline Health code 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g., chloroform Reactivity code 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g., calcium Special hazards (white): no codeNFPA 704 four-colored diamond
Flash point 100 °C (212 °F; 373 K)
200 °C (392 °F; 473 K)
Related compounds
Other anions
Sodium sulfite
Sodium sulfate
Related compounds
Sodium thiosulfate
Sodium bisulfite
Sodium metabisulfite
Sodium bisulfate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
No verify (what is YesYNo ?)
Infobox references

Sodium dithionite (also known as sodium hydrosulfite) is a white crystalline powder with a weak sulfurous odor. Although it is stable in the absence of air, it decomposes in hot water and in acid solutions.

Structure

Raman spectroscopy and single-crystal X-ray diffraction studies reveal that the geometry of the dithionite anion is flexible. The dithionite dianion has C
2
symmetry, with almost eclipsed with a 16° O-S-S-O torsional angle. In the dihydrated form (Na
2
S
2
O
4
·2H
2
O
), the dithionite anion has a shorter S-S bond length and a gauche 56° O-S-S-O torsional angle.[1]

A weak S-S bond is indicated by the S-S distance of 239 pm. Because this bond is fragile, the dithionite anion dissociates in solution into the [SO2] radical anion, as has been confirmed by EPR spectroscopy. It is also observed that 35S undergoes rapid exchange between S2O42− and SO2 in neutral or acidic solution, consistent with the weak S-S bond in the anion.[2]

Preparation

Sodium dithionite is produced industrially by reduction of sulfur dioxide. Several methods are employed, including reduction with zinc powder, sodium borohydride, and formate. Approximately 300,000 tons were produced in 1990.[3]

Properties and reactions

Hydrolysis

Sodium dithionite is stable when dry, but aqueous solutions deteriorate due to the following reaction:

2 S2O42− + H2O → S2O32− + 2 HSO3

This behavior is consistent with the instability of dithionous acid. Thus, solutions of sodium dithionite cannot be stored for a long period of time.[2]

Anhydrous sodium dithionite decomposes to sodium sulfate and sulfur dioxide above 90 °C in the air. In absence of air, it decomposes quickly above 150 °C to sodium sulfite, sodium thiosulfate, sulfur dioxide and trace amount of sulfur.

Redox reactions

Sodium dithionite is a reducing agent. At pH=7, the potential is -0.66 V vs NHE. Redox occurs with formation of sulfite:[4]

S2O42- + 2 H2O → 2 HSO3 + 2 e + 2 H+

Sodium dithionite reacts with oxygen:

Na2S2O4 + O2 + H2O → NaHSO4 + NaHSO3

These reactions exhibit complex pH-dependent equilibria involving bisulfite, thiosulfate, and sulfur dioxide.

With organic carbonyls

In the presence of aldehydes, sodium diothionite reacts either to form α-hydroxy-sulfinates at room temperature or to reduce the aldehyde to the corresponding alcohol above a temperature of 85 °C.[5][6] Some ketones are also reduced under similar conditions.

Applications

Industry

This compound is a water-soluble salt, and can be used as a reducing agent in aqueous solutions. It is used as such in some industrial dyeing processes, primarily those involving sulfur dyes and vat dyes, where an otherwise water-insoluble dye can be reduced into a water-soluble alkali metal salt (e.g. indigo dye).[7] The reduction properties of sodium dithionite also eliminate excess dye, residual oxide, and unintended pigments, thereby improving overall colour quality.

Sodium dithionite can also be used for water treatment, gas purification, cleaning, and stripping. It can also be used in industrial processes as a sulfonating agent or a sodium ion source. In addition to the textile industry, this compound is used in industries concerned with leather, foods, polymers, photography, and many others. Its wide use is attributable to its low toxicity LD50 at 5 g/kg, and hence its wide range of applications. It is also used as decolourising agent in organic reactions.

Biological sciences

Sodium dithionite is often used in physiology experiments as a means of lowering solutions' redox potential (Eo' -0.66 V vs SHE at pH 7).[8] Potassium ferricyanide is usually used as an oxidizing chemical in such experiments (Eo' ~ .436 V at pH 7). In addition, sodium dithionite is often used in soil chemistry experiments to determine the amount of iron that is not incorporated in primary silicate minerals. Hence, iron extracted by sodium dithionite is also referred to as "free iron." The strong affinity of the dithionite ion for bi- and trivalent metal cations (M2+, M3+) allows it to enhance the solubility of iron, and therefore dithionite is a useful chelating agent.

Geosciences

Sodium dithionite has been used in chemical enhanced oil recovery[citation needed] to stabilize polyacrylamide polymers against radical degradation in the presence of iron. It has also been used in environmental applications to propagate a low Eh front in the subsurface in order to reduce components such as chromium.

Photography

It can be used as a developer, but it is a very uncommon choice. It is prone to reduce film speed and, if improperly used, quickly fogs the image.

Laboratory

Aqueous solutions of sodium dithionite were once used to produce "Fieser's solution' for the removal of oxygen from a gas stream.[9] Pyrithione can be prepared in a two-step synthesis from 2-bromopyridine by oxidation to the N-oxide with a suitable peracid followed by substitution using sodium dithionite to introduce the thiol functional group.[10]

See also

External Links

  • Sodium dithionite - ipcs inchem[11]

References

  1. ^ Weinrach, J. B.; Meyer, D. R.; Guy, J. T.; Michalski, P. E.; Carter, K. L.; Grubisha, D. S.; Bennett, D. W. (1992). "A structural study of sodium dithionite and its ephemeral dihydrate: A new conformation for the dithionite ion". Journal of Crystallographic and Spectroscopic Research. 22 (3): 291–301. doi:10.1007/BF01199531. 
  2. ^ a b Catherine E. Housecroft; Alan G. Sharpe (2008). "Chapter 16: The group 16 elements". Inorganic Chemistry, 3rd Edition. Pearson. p. 520. ISBN 978-0-13-175553-6. 
  3. ^ J. J. Barbera, A. Metzger, M. Wolf "Sulfites, Thiosulfates, and Dithionites" in Ullmann's Encyclopedia of Industrial Chemistry 2012, Wiley-VCH, Weinheim. doi:10.1002/14356007.a25_477
  4. ^ Mayhew, S. G. (2008). "The Redox Potential of Dithionite and SO−2 from Equilibrium Reactions with Flavodoxins, Methyl Viologen and Hydrogen plus Hydrogenase". European Journal of Biochemistry. 85: 535–547. doi:10.1111/j.1432-1033.1978.tb12269.x. 
  5. ^ J. Org. Chem., 1980, 45 (21), pp 4126–4129, http://pubs.acs.org/doi/abs/10.1021/jo01309a011
  6. ^ "Aldehyde sulfoxylate systemic fungicides". google.com. Archived from the original on 27 April 2018. Retrieved 27 April 2018. 
  7. ^ Božič, Mojca; Kokol, Vanja (2008). "Ecological alternatives to the reduction and oxidation processes in dyeing with vat and sulphur dyes". Dyes and Pigments. 76 (2): 299–309. doi:10.1016/j.dyepig.2006.05.041. 
  8. ^ MAYHEW, Stephen G. (1978). "The Redox Potential of Dithionite and SO-2 from Equilibrium Reactions with Flavodoxins, Methyl Viologen and Hydrogen plus Hydrogenase". European Journal of Biochemistry. 85 (2): 535–547. doi:10.1111/j.1432-1033.1978.tb12269.x. ISSN 0014-2956. 
  9. ^ Kenneth L. Williamson "Reduction of Indigo: Sodium Hydrosulfite as a Reducing Agent" J. Chem. Educ., 1989, volume 66, p 359. doi:10.1021/ed066p359.2
  10. ^ Knight, David W.; Hartung, Jens (15 September 2006). "1-Hydroxypyridine-2(1H)-thione". Encyclopedia of Reagents for Organic Synthesis. John Wiley & Sons. doi:10.1002/047084289X.rh067.pub2. 
  11. ^ "Sodium dithionite - ipcs inchem" (pdf). www.inchem.org. Berliln, Germany. 2004. Retrieved 15 June 2018. 
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